The structure and dynamics of 2-dimensional fluids in swelling clays   总被引：3，自引：0，他引：3  

Neal T. Skipper  Peter A. Lock  James O. Titiloye  Jan Swenson  Zakaria A. Mirza  W. Spencer Howells  Felix Fernandez-Alonso 《Chemical Geology》2006,230(3-4):182-196

The interlayer pores of swelling 2:1 clays provide an ideal 2-dimensional environment in which to study confined fluids. In this paper we discuss our understanding of the structure and dynamics of interlayer fluid species in expanded clays, based primarily on the outcome of recent molecular modelling and neutron scattering studies. Counterion solvation is compared with that measured in bulk solutions, and at a local level the cation-oxygen coordination is found to be remarkably similar in these two environments. However, for the monovalent ions the contribution to the first coordination shell from the clay surfaces increases with counterion radius. This gives rise to inner-sphere (surface) complexes in the case of potassium and caesium. In this context, the location of the negative clay surface charge (i.e. arising from octahedral or tetrahedral substitution) is also found to be of major importance. Divalent cations, such as calcium, eagerly solvate to form outer-sphere complexes. These complexes are able to pin adjacent clay layers together, and thereby prevent colloidal swelling. Confined water molecules form hydrogen bonds to each other and to the clays' surfaces. In this way their local environment relaxes to close to the bulk water structure within two molecular layers of the clay surface. Finally, we discuss the way in which the simple organic molecules methane, methanol and ethylene glycol behave in the interlayer region of hydrated clays. Quasi-elastic neutron scattering of isotopically labelled interlayer CH₃OD and (CH₂OD)₂ in deuterated clay allows us to measure the diffusion of the CH₃- and CH₂-groups in both clay and liquid environments. We find that in both the one-layer methanol solvates and the two-layer glycol solvates the diffusion of the most mobile organic molecules is close to that in the bulk solution.  相似文献   

Mineral and fluid inclusions in zircon of UHP metamorphic rocks from the CCSD-main drill hole: A record of metamorphism and fluid activity   总被引：18，自引：0，他引：18  

Zeming Zhang  Kun Shen  Yilin Xiao  Jochen Hoefs  J.G. Liou 《Lithos》2006,92(3-4):378-398

The Chinese Continental Scientific Drilling (CCSD) main drill hole (0–3000 m) in Donghai, southern Sulu orogen, consists of eclogite, paragneiss, orthogneiss, schist and garnet peridotite. Detailed investigations of Raman, cathodoluminescence, and microprobe analyses show that zircons from most eclogites, gneisses and schists have oscillatory zoned magmatic cores with low-pressure mineral inclusions of Qtz, Pl, Kf and Ap, and a metamorphic rim with relatively uniform luminescence and eclogite-facies mineral inclusions of Grt, Omp, Phn, Coe and Rt. The chemical compositions of the UHP metamorphic mineral inclusions in zircon are similar to those from the matrix of the host rocks. Similar UHP metamorphic P–T conditions of about 770 °C and 32 kbar were estimated from coexisting minerals in zircon and in the matrix. These observations suggest that all investigated lithologies experienced a joint in situ UHP metamorphism during continental deep subduction. In rare cases, magmatic cores of zircon contain coesite and omphacite inclusions and show patchy and irregular luminescence, implying that the cores have been largely altered possibly by fluid–mineral interaction during UHP metamorphism.

Abundant H₂O–CO₂, H₂O- or CO₂-dominated fluid inclusions with low to medium salinities occur isolated or clustered in the magmatic cores of some zircons, coexisting with low-P mineral inclusions. These fluid inclusions should have been trapped during magmatic crystallization and thus as primary. Only few H₂O- and/or CO₂-dominated fluid inclusions were found to occur together with UHP mineral inclusions in zircons of metamorphic origin, indicating that UHP metamorphism occurred under relatively dry conditions. The diversity in fluid inclusion populations in UHP rocks from different depths suggests a closed fluid system, without large-scale fluid migration during subduction and exhumation.  相似文献   

黄河源地区草地退化空间特征   总被引：54，自引：4，他引：54  

张镱锂  刘林山  摆万奇  沈振西  阎建忠  丁明军  李双成  郑度 《地理学报》2006,61(1):3-14

利用黄河源地区1985年和2000年1：100000土地利用／覆被数据，结合1：250000DEM、道路和居民点数据与野外调查资料，分析草地退化与坡向、海拔及距道路和居民点距离之间的关系．探讨黄河源区15年间土地覆被变化特征与规律。结果表明，退化草地占源区总面积的8．24％，冬春季牧场退化率显著高于夏季牧场：草地退化是黄河源区研究时段内土地利用／覆被变化最主要的特征。草地退化表现为：①阳坡退化率高于阴坡；②受人口密度影响，草地退化率与海拔高度成反比，相关系数为．0．925；③距离居民点越近。退化率越高。尤其当与居民点距离≤12km时，草地退化率与其相关系数高达-0．996；④在距道路4km以内．草地退化率与道路距离成反比．相关系数高达-0．978。1985年以来，源区的草地退化有自然因素的影响．但人类活动的影响仍起主导作用。科学地减少当地居民对草地的过分依赖是解决脆弱的江河源区环境退化的根本。  相似文献   

Source parameters of microearthquakes at Mount St Helens (USA)   总被引：1，自引：0，他引：1  

Giuseppina Tusa  Alfonso Brancato  Stefano Gresta  Stephen D. Malone 《Geophysical Journal International》2006,166(3):1193-1223

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The role of friction and secondary flaws on deflection and re-initiation of hydraulic fractures at orthogonal pre-existing fractures   总被引：1，自引：0，他引：1  

Xi Zhang  Robert G. Jeffrey 《Geophysical Journal International》2006,166(3):1454-1465

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Reply to comment by Y. Park and J.-H. Ree on 'Chemical remagnetization of the Upper Carboniferous-Lower Triassic Pyeongan Supergroup in the Jeongseon area, Korea: fluid migration through the Ogcheon Fold Belt'     

Yong-Hee Park  Seong-Jae Doh  Dongwoo Suk 《Geophysical Journal International》2006,167(1):20-23

In their comment, Park & Ree have raised several points against the interpretation by Park et al. , and argued that the remagnetization in the Jeongseon area was caused by the thermal effects of a Late Cretaceous pluton and/or associated short-range hydrothermal fluids, rather than by long-range fluids advocated by us.
We disagree with most points raised by Park & Ree and we make a case that these are invalid because of what we believe is incorrect geologic evidence. Hence, our model—that the fluids causing the chemical remagnetization might migrate through the fault system within the Ogcheon Fold Belt—is the most plausible scenario. We recognize that our model needs to be tested in a future study and we welcome new interpretations for or against our model based on reliable geologic or geophysical data.  相似文献   

The Dahuiyeh (Zarand) earthquake of 2005 February 22 in central Iran: reactivation of an intramountain reverse fault   总被引：3，自引：0，他引：3  

M. Talebian  J. Biggs  M. Bolourchi  A. Copley  A. Ghassemi  M. Ghorashi  J. Hollingsworth  J. Jackson  E. Nissen  B. Oveisi  B. Parsons  K. Priestley  A. Saiidi 《Geophysical Journal International》2006,164(1):137-148

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Probabilistic local waveform inversion for moment tensor and hypocentral location   总被引：3，自引：0，他引：3  

Zoltán Wéber 《Geophysical Journal International》2006,165(2):607-621

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粤北地区产铀岩体的铀矿化特征及其成矿机制探讨   总被引：7，自引：0，他引：7  

张敏  陈培荣  陈卫锋 《化工矿产地质》2006,28(1):9-14,26

粤北地区是中国花岗岩型铀矿最为重要的大型矿聚集区,其主要的产铀花岗岩体是诸广山岩体和贵东岩体,均为多期多阶段的复式岩体,主要以印支期和燕山期的花岗岩为主。粤北地区的铀矿床主要由诸广山的长江铀矿田、澜河铀矿田、鹿井铀矿田和贵东岩体的下庄铀矿田组成,根据铀的成矿特征可分为硅化带型、交点型和碱交代型。粤北地区的铀成矿流体主要来自于地幔,而不是以往认为的花岗岩浆期后热液,铀源主要是粤北产铀岩体的印支期花岗岩。因此在华南开展新一轮铀矿找矿时,跳出以往“沿带找矿”的老思路,聚焦于印支期岩浆作用与铀矿床的关系,并重点关注华南地区可能的地幔柱或热点区域。  相似文献   

从流体包裹体特征探讨泥堡金矿成因   总被引：5，自引：1，他引：5  

刘平  杜芳应  杜昌乾  雷志远  樊正烈  徐石辉  阚小波 《贵州地质》2006,23(1):44-50

泥堡金矿床据脉石矿物和萤石的包裹体研究,包裹少而小,类型较为简单。综合包裹体各项参数和气液成分分析认为,成矿流体属NaCl-H_2O体系的富K~ 的、弱酸性溶液,具有较高密度、较低盐度和中-低温度的特点。结合硫和氢氧同位素测定结果,成矿流体是燕山运动阶段的地表水沿断裂深循环,特别是在富K、富Au的凝灰岩中往复循环作用形成的。当各种条件具备时即可卸载成矿,成矿的最佳位置就是沿P_(2-3)β_1与P_2m~(dc)之间沉积间断面发生的层间滑动构造带。  相似文献